Printing at 0.1 takes a fair amount of tuning to get right. I have printed a thing or two at this fine of a resolution, but just to see if I could, really. My default settings are 0.2.
In your settings for skeinforge, you will need to change the ratio for carve and infill to print at 0.1. The ratio is layer width to layer height. I believe the default ratio is 1.8 with a layer height of 0.3. This results in a width of 0.54 mm.
You can't realistically print at a width of less than your nozzle diameter (0.4 mm). So, if you really want to try to print at 0.1 mm layer height, your ratios must be at least 4.0.
For Slic3r, though, it should be doing this for you automatically assuming you have the nozzle diameter set correctly and it is properly calibrated.