"But I can't find anywhere if this is the V+ or GND pin"
IO pin flip from gnd to their vcc (3.3v in this case)
IO pins can both source and sink current. So can be used as a + or a gnd pin.
but care must be taken not to exceed their source or sink limits for the pin (not all pins are equal)
If you want the led to be on when the IO pin is on, your using the pin as source, the other led leg should be grounded.
If you want the led to be on when the IO pin is off, your using the pin as a sink, the other led leg should be on vcc.
Most IO pins on the LPC1768/9 are 5v tolerant when in IO mode (not when analog mode)
But not all...
When you dealing with electronics is always best to check the datasheet [
www.nxp.com]
search for P1[18] and P1[23], both are 5v tolerant.
Also remember that LEDs have polarity. It only works one way around.